Sebastian Trippel,1 Terry Mullins,1 Nele L. M. Müller,1 Jens S. Kienitz,1,2 Rosario González-Férez,2,3 and Jochen Küpper1,2,4
1Center for Free-Electron Laser Science, DESY, Notkestrasse 85, 22607 Hamburg, Germany
2The Hamburg Center for Ultrafast Imaging, University of Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany
3Instituto Carlos I de Física Teórica y Computacional and Departamento de Física Atómica, Molecular y Nuclear, Universidad de Granada, 18071 Granada, Spain
4Department of Physics, University of Hamburg, Luruper Chaussee 149, 22761 Hamburg, Germany
(published 10 March 2015)
Abstract
We demonstrate strong laser-field-free orientation of absolute-ground-state carbonyl sulfide molecules.The molecules are oriented by the combination of a 485-ps-long nonresonant laser pulse and a weak static electric field. The edges of the laser pulse create a coherent superposition of two rotational states resulting in revivals of strong transient molecular orientation after the laser pulse. The experimentally attained degree of orientation cos θi ≈ 0.6 corresponds to the theoretical maximum for mixing of the two states. Switching off the dc field would provide the same orientation completely field free.
Sub-micron proximal probe thermal desorption and laser mass spectrometry on painting cross sections (Anal. Methods 2014 pdf link)